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Bacterial anaerobic corrosion : ウィキペディア英語版
Bacterial anaerobic corrosion

Bacterial anaerobic corrosion is a bacterially-induced oxidation of metals.
In a humid environment and anoxic conditions the corrosion of metals occurs as a result of a redox reaction that generates molecular hydrogen from hydrogen ions, requiring bacteria, unlike anaerobic corrosion that occurs spontaneously.
A base metal, such as iron (Fe) goes into aqueous solution as positively charged cation, Fe2+. As the metal is oxidized under anaerobic condition by the protons of water, H+ ions are reduced to form molecular H2. This can be written in the following ways under acidic and neutral conditions respectively:
:Fe + 2 H+  →  Fe2+ + H2
:Fe + 2 H2O  →  Fe(OH)2 + H2
Usually, a thin film of molecular hydrogen forms on the metal. Sulfate-reducing bacteria, oxidize the molecular hydrogen to produce hydrogen sulfide ions (HS) and water:
:4 H2 + SO42−  →  HS + 3 H2O + OH
The iron ions partly precipitate to from iron (II) sulfide. A reaction with water also occurs, producing iron hydroxide.
:Fe2+ + HS  →  FeS + H+
:3 Fe2+ + 6 H2O  →  3 Fe(OH)2 + 6 H+
The net equation comes to:
:4 Fe + SO42− + H+ + 3 H2O  →  FeS + 3 Fe(OH)2 + OH
This form of corrosion by sulfate-reducing bacteria can, in this way, be far more harmful than anaerobic corrosion.
==See also==

*Corrosion

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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